TOKUSHIMA-KAIGO.COM Library

Solid State Physics

Diffusion and Reactivity of Solids by James Y. Murdoch, Ying Bai, Khairul Basar, Liquan Chen,

By James Y. Murdoch, Ying Bai, Khairul Basar, Liquan Chen, Loredana De Rogatis

This booklet is dedicated to the physics, chemistry and fabrics technology of diffusion, mass shipping, and reactivity of solids, together with: physics and chemistry of defects in solids; reactions in and on solids, e.g. intercalation, corrosion, oxidation, sintering; and ion shipping measurements, mechanisms and concept.

Show description

Read Online or Download Diffusion and Reactivity of Solids PDF

Similar solid-state physics books

Glasses and Amorphous Materials

Fabrics technological know-how and expertise is a seminal paintings and crucial reference supplying entry to a veritable compendium of knowledge protecting crucial periods of fabrics present in undefined, together with: metals, ceramics, glasses, polymers, semiconductors and composites. also, fabrics technological know-how and expertise bargains with the purposes, processing, and basic ideas linked to those fabrics.

Basic Electromagnetism and Materials

Easy Electromagnetism and fabrics is the manufactured from decades of training simple and utilized electromagnetism. This textbook can be utilized to educate electromagnetism to quite a lot of undergraduate technology majors in physics, electric engineering or fabrics technological know-how. even if, by way of making lesser calls for on mathematical wisdom than competing texts, and through emphasizing electromagnetic homes of fabrics and their purposes, this textbook is uniquely fitted to scholars of fabrics technology.

Multifrequency Electron Paramagnetic Resonance: Theory and Applications

Filling the space for a scientific, authoritative, and updated assessment of this state of the art method, this e-book covers either high and low frequency EPR, emphasizing the significance of adopting the multifrequency method of research paramagnetic structures in complete element through the use of the EPR approach. In so doing, it discusses not just the underlying idea and purposes, but in addition all fresh advances -- with a last part dedicated to destiny views.

Fundamentals of Amorphous Solids: Structure and Properties

Lengthy awaited, this textbook fills the space for convincing techniques to explain amorphous solids. Adopting a special method, the writer develops a framework that lays the principles for a idea of amorphousness. He unravels the clinical mysteries surrounding the subject, exchanging really imprecise notions of amorphous fabrics as disordered crystalline solids with the well-founded notion of perfect amorphous solids.

Extra info for Diffusion and Reactivity of Solids

Example text

Again, all the characteristic bands of Co2O3 and Co3O4 are observed in the soaked materials, indicating clearly that Co2O3 and Co3O4 are the main produced components in the material, consistent with the results of XRD analysis. Comparing the relative intensities of the spectral peaks of Co2O3 and Co3O4 in the material, we can see that the content of LiCoO2 is lower in Al2O3-coated LiCoO2 than in bare LiCoO2. Meanwhile, it is also found that the content ratio of Co2O3/Co3O4 is higher in Al2O3coated LiCoO2 than in bare LiCoO2, verifying the above proposal.

A reasonable explanation is that fewer Co2+ ions are converted from Co3+ or lost for the Al2O3coated nano-LiCoO2 than for the bare nano-LiCoO2. As Co2+ is stable in liquid while Co3+ is stable in solid, it is proposed that Li+ ion extraction from LiCoO2 and the oxidation of the solvent result in the formation of Co2O3 in Al2O3-coated LiCoO2 and Co3O4 in bare LiCoO2, respectively. This proposal is verified with the following structural characterization of the generated solids by XRD and Raman spectroscopy.

The main generated species have C-O-C and O=C structures. The former, consistent with that of liquid GC-MS results, confirms the existence of poly(ethylene oxide) (PEO)-like polymeric species while the latter demonstrates the formation of carbonates and other carbonyl groups in the liquid. These carbonates might include various solvable (lithium) alkyl carbonates. It is worth pointing out that the vibration bands close (with position difference ≤ ±6cm-1 vs the instrumental resolution of 4cm-1) to that of EC or DMC are not considered in this chapter.

Download PDF sample

Rated 4.91 of 5 – based on 24 votes